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copolymerization

Copolymerization

To the best of our knowledge, this is the first successful example of the alternating copolymerization of CO 2 and CHO under 1-atm CO 2. The alternating copolymerization under 1-atm CO 2 proceeded very slowly but surely even at 25 °C to generate polycarbonate (yield = 25 %, M n = 1,800, M w /M n = 1.6) ( Table 1 , run 3).

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